The problem with that is, few of them can wrestle and most of them will bury a good deal of talent on the mic. And even those that do wrestle probably have some rust, which won't help in putting them over.
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The Night of Champions guests are major league stars while the "young talent" are mere AAA journymen. The only person I can see putting anybody over would be the Rock but he is above the wrestling business now so it won't happen..... the only option is to bring in the Attitude Era Champions as managers and pray that they do a better job than what Roddy Pipper did on Smackdown.